Organic Chemistry and Unit Processes : 2130501 Term Dates : 04-07-2016 to 02-12-2016

Academic Calendar of GTU

Syllabus 

To all our new and old students.
       Welcome to the new semester!

      I look forward to working with you over the next 19 weeks in  OC&UP(2131301). Get ready for a journey of a lifetime learning memories. In this course you will learn about general organic chemistry and unit processes Stereochemistry, Petroleum Chemistry, Colour,  Dyes and Pigments and many more topics which will help you to gain a vast knowledge regarding basic chemistry behind the synthesis of chemical. in addition to this some topics like, Synthetic Drugs, Amino acid & Protein Chemistry and  Hetero-cyclic Compounds will also guide you to get required knowledge regarding the emerging and developing field of biochemical engineering.

Weekly participation in 3 lectures and one laboratory of 2 hours are essential throughout the course to be successful in the subject. 

This course will have 7 Labs, 5 Hand written assignments, One power point presentation, One active learning assignment in MS-Word file. One Open Ended Project work.

Hope that all you will come with   "Assignment:0 Prerequisite" completed.

We hope that, once more it will a good and interesting course program for you. Even though we have tried to finalize our scheduling and class rooms allocations, Class room and time changes may occur. Therefore, we would like to ask you to frequently check our notice boards for notifications and updates. It is also advised to visit this blog frequently for getting new learning experiences, learning materials or some instructions.

There are two divisions as following 
Division-1 150190105001 to 150190105066    1 to 21 Batch 31,    22 to 41 batch 32,     42 to 66 Batch 33
Division-2 150190105067 to 150190105126    67 to 92 Batch 35    93 to 113 batch 36    114 to 126 Batch 37

Assignment:0 Prerequisite 

1.            Write 50 IUPAC names of organic molecules and draw their structures.

2.             Draw 50 structures of organic molecules and write their IUPAC names. 

Assignment:1 

1.            Differentiate fission and fusion reaction with two examples.

2.            Define the terms: Free Radical, Carbonium, Carbanion, Carbenes and Nitrenes. Nucleophilles and Electrophilles with suitable example and figure.

3.            What are SN1 and SN2 reactions explain with examples one of each.

4.            Describe four main types of organic reactions.

5.            Explain the manufacturing process of Acetic acid

6.             Explain mechanism of   Esterification with an example.

7.             Discuss Strengths of Acids.

8.            Explain the nomenclature of carboxylic acids. 

9.             Give manufacturing process of following acids : Formic acid, Oxalic acid, Palmitic acid & Stearic acid with suitable illustrations. 

Assignment:2

1.            Define Optical, Geometrical and Conformational Isomerism with proper examples.

2.             What is call optical activity with respect to organic compounds?

3.            Explain Polarimeter with its instrumentation, working and importance.

4.            Define specific rotation with importance.

5.            Explain the concept of Diasteromers, Enantiomers and meso compound with the example of lactic acid and tartaric acid.

6.            Explain E and Z designation with two examples.

7.            How would you carried out Resolution of (i) racemic mixture of acids and (ii) racemic mixture of bases?

8.            Differentiate between unit process and unit operation Discuss the advantages of continuous process and batch process over each other.

9.            Finde out the absolute configuration of followings.

10.           Define nitration. Enlist various nitrating agents and discuss the function of sulphuric acid in the mixed acid used for nitration

11.           Describe the batch nitration of benzene with mixed acid Give an account on methods of reduction for the preparation of amines. Illustrate various products of reduction of nitrobenzene

12.           Explain kinetics and mechanism of aromatic nitration. What is the        effect of Nitrous acid on nitration

13.           Describe the manufacture of p – nitro acetanilide Define unit process. Why is it so called? How do unit processes differ from unit operation?

14.           Give a brief account of nitration of paraffinic hydrocarbon Give evidence to establish the formation of nitryl ions in a nitration process conducted using mixed acids

15.           Describe following unit processes –with suitable industrial important chemicals: Amination, Hydrogenation, Halogenations, Oxidation and Reduction.

16.          Explain following unit processes –with suitable industrial important chemicals: Sulphonation, Hydrolysis, Alkylation and Polymerization.

Assignment:3 

1.            What is polynuclear compound. Write preparation, properties and uses of Naphthalene, 

2.            write structural formula of anthracene and  give one preparation and three reactions.

3.            What is heterocyclic compound? give synthesis and reactions of pyrrole and Furan.

4.            Write about nomenclature of heterocyclic comppounds.

5.            Give one synthesis and two uses of each: Thiophene, Pyridine and Quinoline.

6.            Write about the chemical properties of Thiophene, Pyridine and Quinoline.

7.            Compare the physical properties of Thiophene, Pyridine and Quinoline, Furan, Naphthalene, Anthracene.

8.            Explain the term carbohydrates. And give classification.

9.            Give two chemical reactions of each: Glucose, Fructose and Starch.

10.          Give the conversion of any aldose to ketose and ketose to aldose.

11.          Give conversion of pentose to hexasose.

12.          Explain the manring of cane sugar from sugarcane with flow sheet.

Assignment:4

1.            Define the terms i) Aminoacid ii) alpha amino acid iii) Protien

2.            Prepare a note on  qualitative tests of proteins.

3.            Give any three synthesis of aminoacids.

4.            Give properties of aminoacids.

5.            What is amphoteric nature of amino acid?

6.            explain isoelectric point.

7.            Prepare a note on Primary, Secondary, Tertiary and Quartanery Structure of Protein.

8.            What are RNA and DNA. give types of RNA.

9.            Explain the importance of DNA and its structure.

10.          Write mechanism and four uses of these reactions: Canninzaro, Wolf Kishner and Clasien.

11.          What is call diazotisation? Explain with importance in different chemical manufacturing.

12.          Explain sandmayer reaction with mechanism.

13.          Compile some facts like General reaction, Mechanism, examples and applications on Curtius reaction.

14.          What is Baeyer Villiger oxidation reaction? Give mechanism and application.

15.          Give some applications of Hoffman degradation reaction with any one mechanism .

16.          Prepare a note with General reaction, Mechanism, examples and applications of the Michael and Dieckmann reactions.

17.          What is Drug and Medicine?

18.          What are Antiseptics? Give an example with synthesis.

19.           What are Antimalarials? give two examples and any one synthesis.

20.          Explain the term 'Antibacterials' and suggest an example with synthesis.

21.          Give classification of drug according to their therapeutic uses with examples.

Assignment: 5

1.            Give synthesis and uses of Sulphanilamide, Sulphaguanidine, Chloromycetin, and Chloroquine. 

2.            Write the difference between Colour,  Dyes and Pigments.

3.            Give classification of dyes based on Application and structural representation with an example of each.

4.            What are chromophore and auxochrome explain with examples.

5.            Prepare a note on theories of colour.

6.            Write a note on application of dyes and pigments.

7.            Give preparation of dyes: Congo  red,  Malachite  Green,  Crystal  Violet, Alizarin, Phenolphthalein, Fluorescein, Eosin and Indigo.

8.            Write a note on occurrence and composition of crude oil.

9.            Explain the distillation of the Crude oil.

10.          Explain the terms:  Cracking, Knocking, Octane  Number  &  Cetane  Number.

11.          What is Synthetic petrol write any one method of preparation of synthetic petrol.

List of practicals to be performed in the Labs.

NO	TOPIC
1	To determine the melting Point of the given compound.
2	Preparation of Acetanilide from Aniline.
3	To determine flow rate of different organic compound by paper chromatography.
4	To prepare Acetylsalicylic acid from salicylic acid.
5	To synthesize Sudan‐I dye from             aniline and β‐naphthol.
6	To identify unknown organic compound.………………………..
Practicals Based on Latest Outcomes in Technology Study
7	Determination of moiture containt in given sample by Infrared moiture balance.

Assignment Submission Dates:

Sr. No	Assignments no. / Unit	Expected Date
1	Assignment:1	06-08-2016
2	Assignment:2	06-09-2016
3	Assignment:3	30-09-2016
4	Assignment:4	21-10-2016
5	Assignment:5	02-12-2016

NOTE:

For Word file Size A4, font Times new roman: Title 14 Bold, Subtitle 13 normal, matters should be in 12 normal, All paragraphs should be justified, images should be sent as jpeg/png format sepratly with the mail, reactions and structures should be drawn in the ACD/ChemSketch software.Freeware link

The word, ppt and SAQ files can be sent on Email id ocupjuly2016@gmail.com

File Names must be as follows : 

For word file Enrlnumber_2130501_Word.doc    example : 1234567890_2130501_Word.doc

For ppt    file Enrlnumber_2130501_PPT.ppt       example : 1234567890_2130501_PPT.ppt     PPT Format

For SAQ file Enrlnumber_2130501_SAQ.doc     example : 1234567890_2130501_SAQ.doc   SAQ Format

NPTEL Video or other related video must be in MP4 format resolution >=360, you can use internet at our laboratory.

Word file Topics:

150190105001	Introduction of general principles of organic reactions and mechanism  and type of fission reaction
150190105002	Types of reaction Intermediates
150190105003	Types of Reagents
150190105004	Define the Organic Reaction by Substitution and Addition Reaction
150190105005	Define the Organic Reaction by Elimination,Rearrangement and Polymerization Reaction
150190105006	Introduction of Stereo Chemistry and Define Optical activity
150190105007	Define Plane- polarized light,Pane of symmetry and chiral, Specific Rotation
150190105008	Optical activity in Lactic and Tartaric Acid
150190105009	R and S notification of optically active compound
150190105010	E and Z system for geometrical Isomer and Resolution of racemic mixture
150190105011	Introduction of various processes and operations  and
150190105012	Nitration and Amination
150190105013	Hydrogenation and it's application
150190105014	Halogenation and it's application
150190105015	Oxidation and its advantages and disadvantages
150190105016	Reduction and it's advantages and disadvantages
150190105017	Alkylation
150190105018	Sulphonation and Hydrolysis
150190105019	Polymerization and it's applications
150190105021	Unit Operation
150190105022	Separation processes
150190105023	Purification
150190105024	Reaction processes
150190105025	Heat exchangers
150190105026	Introduction of Carboxylic acid and nomenclature
150190105027	Manufacture,Properties and uses of Acetic acid
150190105028	Manufacture ,properties and uses of Formic acid
150190105029	Manufacture ,properties and uses of Oxalic acid
150190105030	Manufacture , Reactions palmitate acid and Stearic acid
150190105031	Manufacture, properties and Uses of Acid amide and Ester
150190105032	Manufacture,Properties and uses of Acid chloride
150190105033	Manufacture,properties and uses of Acid anhydride  and other reaction of carboxylic acid
150190105034	Introduction of Poly-nuclear and hetero cyclic compound
150190105035	classification of Poly-nuclear and hetero-cyclic compound
150190105036	Naphthalene
150190105037	Anthracene
150190105038	Pyrrole
150190105039	Furan
150190105040	Thiophene
150190105041	Pyridine
150190105042	Quinoline
150190105043	Diazotization
150190105044	Sandmeyar and Cannizaro Reaction
150190105046	Wolf kishner Reduction and Clasien and Cartius Reaction
150190105047	Baeyar-Villiger and Hoffmann Reaction
150190105048	Michael additional Reaction and Dieckmann condensation
150190105050	Introduction and classification of Carbohydrate
150190105051	D and L designation of saccharides and configuration of D-glucose
150190105054	Reaction of D-glucose
150190105055	Configuration and Reaction  of D-Fructose
150190105056	Starch
150190105058	conversion of higher to lower aldose and lower to higher aldose
150190105059	conversion of ketose to aldose and aldose to ketose  and manufacture of cane suger
150190105060	Introduction of amino acid and protein chemistry and classification of protein
150190105061	Isolation and Qualitative test of protein
150190105062	classification and reaction of amino acid
150190105063	structure of protein,DNA and RNA
150190105064	Introduction of synthetic drugs
150190105065	Antiseptic,Halogenated Antiseptic,Antimalarial drug
150190105066	Quinidine, Antibacterial and sulpha drug
150190105067	sulpha drug
150190105068	Types  of fission reaction and types of Reagents
150190105069	Types of Reaction Intermediates
150190105070	Nucleophilic Substitution reaction
150190105072	Electrophilic  Substitution reaction
150190105074	Classification Of amino acid
150190105075	additional reaction
150190105076	elimination reaction
150190105078	rearrangement reaction and polymerization reaction
150190105079	introduction to stereo chemistry
150190105081	optical activity
150190105083	plane polarized light and plane of and chiral symmetry
150190105084	measurment of optical activity and speafic rotation
150190105085	optical activity in lactic and tarteric acid
150190105086	R and S notification of optical activity compound
150190105087	Resolution  of recemic Mixture
150190105089	Nitration Process
150190105090	Amination and Hydrogenation process
150190105091	Halogenation process
150190105092	Oxidation process
150190105093	Reduction process
150190105094	Sulphonation process
150190105095	Hydrolysis process
150190105096	Alkynation of any four types
150190105097	Condensation and addition polymerisation
150190105098	Explain the separation process
150190105099	Explain purification and reaction process
150190105100	Explain heat exchangers
150190105101	Method of preparation of carboxylic acid
150190105102	Note on acetic acid
150190105103	Explain about formic acid
150190105104	Explain about Palmitic acid
150190105105	Derivatives of carboxylic acid
150190105106	Preparation,propertis and chemical reaction of napthalene
150190105108	Preparation,propertis, chemical reaction and uses of anthracene
150190105109	classification of protein and isolation of protein
150190105110	Preparation,propertis and chemical reaction of Furan
150190105111	Preparation,propertis and chemical reaction of Thiopene
150190105112	Preparation,propertis and chemical reaction of pyrinine
150190105113	Synthesis properties and chemical reaction of quinonine
150190105114	Explain Diazotisation
150190105115	Sandmeyer and cannizaro reaction
150190105116	Wolfkishner and Clasien reaction
150190105117	Cartins and Bayers vulnerisation
150190105118	Hoffman and michael additional reaction
150190105119 150190105120	Classification of carbohydrates and D and L designation of saccharide Turbidity and its measurement with applications
150190105121	Configuration of D glucose
150190105122	Reaction of D glucose
150190105123	Configuration and reaction of D fructose
150190105124	Synthesis of amino acid amphoteric nature and isoelectric point of α-amino acid
150190105126	Preparation,propertis and chemical reaction of Pyrrole
D2D-1	phenacetin drug
D2D-2	paracetamol drug
D2D-3	sulphanilamide drug
D2D-4	sulphaguanidine drug
D2D-5	chloroquine drug
D2D-6	classification of dye based on application
D2D-7	classification of dye based on structure
D2D-8	congo red dye
D2D-9	malachite green dye
D2D-10	alizarin dye (anthraquinone dye)
D2D-11	eosin dye
D2D-12	indigo dye(vat dye)
D2D-13	crystal voilet dye
D2D-14	phenolphthalein dye (triarylmethane dye)
D2D-15	Esterification process
D2D-16	Amination Process
D2D-17	Anthraquinone dyes
D2D-18	Diasteromers
D2D-19	E and Z designation
D2D-20	Resolution of racemic mixture
D2D-21	Acid Amides
D2D-22	Acid Anhydrides
D2D-23	Stearic acid
D2D-24	Composition of Crude oil
D2D-25	Distillation of the Crude oil
D2D-26	Synthetic petrol.(Two Methods)
D2D-27	Antibacterial Drugs
D2D-28	A note on Paracetamol
D2D-29	A note on Phenacetin
D2D-30	A note on Sulphanilamides
D2D-31	Hoffman Reactions
D2D-32	Naphthalene as aromatic compound
D2D-33	Baeyer Villiger oxidation reaction
D2D-34	Thiophene
D2D-35	Pyridine
D2D-36	Quinoline

ppt /Video file.... topics

150190105001	About S block of periodic table
150190105002	About P block of periodic table
150190105003	About D block of periodic table
150190105004	Nomenclature rules of organic compounds
150190105005	Fission reactions
150190105006	Free redicals ,Carbonium and nitrenes
150190105007	Carbanion and carbenes
150190105008	Nucleophilles and Electrophilles
150190105009	Diffrent types of organic reactions
150190105010	Adition reactions
150190105011	Purification of organic compounds
150190105012	Composition of organic compounds
150190105013	Structures of organic molecules
150190105014	Isomerism
150190105015	Spectroscopy
150190105016	Alkanes
150190105017	Alkenes
150190105018	Alkynes
150190105019	Alkyl Halides
150190105021	Alcoholes
150190105022	Aldyhides
150190105023	Carboxylic acids
150190105024	Amines
150190105025	Esters
150190105026	Aromatic compounds
150190105027	Optical activity
150190105028	Racemic mixtures and their resolutions
150190105029	Nitration process
150190105030	Amination process
150190105031	Hydrohelogenation and helogenation process
150190105032	Oxidation and reduction process
150190105033	Sulphonation process
150190105034	Alkylation
150190105035	Polynuclear compounds
150190105036	Heterocyclic compounds
150190105037	Classification of carbohydrates
150190105038	Configuration and chemical reactions of saccharides
150190105039	Protein chemistry
150190105040	Coloures
150190105041	Dyes
150190105042	Pigments
150190105043	Occurance and compositions of crude oil
150190105044	Balancing chemical equations
150190105046	Substitution Reactions
150190105047	The Helogens
150190105048	The carbon Group
150190105050	The nitrogen group
150190105051	The oxygen group
150190105054	The nobel gases
150190105055	Safety Precautions in OC&UP laboratory
150190105056	SN1 and SN2 reactions
150190105058	Functional Groups Of organic chemistry
150190105059	Stereochemistry
150190105060	Atoms,molecules and ions
150190105061	Substitution Reactions
150190105062	Antibiotics
150190105063	Distillation of cruid oil
150190105064	Octane number and cetane number
150190105065	Synthetic petrol
150190105066	Synthetic polymers
150190105067	Steroids
150190105068	Ketons
150190105069	Polymerization Process
150190105070	Elimination reactions
150190105072	About Benzene
150190105074	Geometrical and Conformational Isomerism
150190105075	Diasteromers
150190105076	Hydrolysis process
150190105078	Preparation, properties and manufacture of Acetic Acid
150190105079	Preparation, properties and manufacture of Formic Acid
150190105081	Preparation, properties and manufacture of Oxalic Acid
150190105083	Acid Anhydrides and Chlorides
150190105084	Mechanism of Esterification and strengths of acids
150190105085	Drugs details, their advantages and drawbacks
150190105086	Vitamins
150190105087	Nitration process and its industrial application.
150190105089	Amination process and its industrial application
150190105090	Hydrogenation process and it's industrial application
150190105091	Halogenations process and its industrial application
150190105092	Derivativatives of Carboxylic Acid
150190105093	Oxidation and Reduction Reaction.
150190105094	Mechanism of Esteriofication.
150190105095	Sulphonation process and its industrial application.
150190105096	Hydrolysis process and it's industrial application.
150190105097	Alkylation and polymerisation process
150190105098	Manufacture process of Oxalic Acid
150190105099	Types of Organic reactions and its mechanism.
150190105100	Nucleophillic Addition Reaction.
150190105101	Electrophilic Addition Reaction
150190105102	Nucleophillic Substitution Reaction.
150190105103	Electrophilic Substitution Reaction
150190105104	Polynuclear And heterocyclic compound
150190105105	Preparation,properties and uses of Napthalene.
150190105106	Optical, Geometrical and Conformational Isomerism.
150190105108	Optical activity in Lactic and Tartaric acid.
150190105109	R and S configuration of Optically active compound .
150190105110	E and Z designation of Geometrical isomers.
150190105111	Introduction, Preparation and Properties of Carboxylic Acid
150190105112	Manufacture Process of Acetic acid.
150190105113	Manufacture Process of Formic acid.
150190105114	Preparation,properties and uses of Anthracene.
150190105115	Preparation,properties and uses of Pyrrole.
150190105116	Preparation,properties and uses of Furan.
150190105117	Preparation,properties and uses of Thiophene.
150190105118	Preparation,properties and uses of Pyridine.
150190105119 150190105120	Preparation,properties and uses of Quinoline. Turbidity and its measurement
150190105121	Application of Diazotisation Reaction.
150190105122	Application of Sandmeyer Reaction.
150190105123	Application of Cannizaro Reaction
150190105124	Application of Wolf Kishner Reaction
150190105126	Application of Clasien, Curtius Reaction
D2D-1	Application of Baeyyer Villiger Reaction
D2D-2	Application of Hoffman and Michael Dieckmann reaction.
D2D-3	Introduction and classification to CARBOHYDRATES.
D2D-4	Configuration and Chemical reaction of Carbohydrates.
D2D-5	Killiani Synthesis, Ruff & Wohl’s Degradation
D2D-6	Conversion of Aldose to Ketose.
D2D-7	Manufacturing of Cane Sugar from Sugarcane with flow sheet.
D2D-8	Introduction and classification of Protein.
D2D-9	Composition and Isolation of Protein.
D2D-10	Classification of Amino acids & their synthesis.
D2D-11	Primary, Secondary, Tertiary and Quartanery Structure of Protein.
D2D-12	RNA AND DNA
D2D-13	Synthesis of Drugs and Antiseptics.
D2D-14	synthesis of Halogenated compounds and Antimalarials.
D2D-15	Classification of dyes based on Application and Structural representation.
D2D-16	Synthesis of Antibacterials and Sulpha Aspirin.
D2D-17	Synthesis of Phenacetin and Paracetamol.
D2D-18	synthesis of Sulphanilamide and Sulphaguanidine.
D2D-19	Synthesis of Chloromycetin and Chloroquine.
D2D-20	Quinonoid Theory
D2D-21	Valence Bond Theory
D2D-22	molecular orbitaol theory
D2D-23	Application of Dyes and Pigments.
D2D-24	Preparation of Congo red.
D2D-25	Preparation of Malachite Green.
D2D-26	Preparation of Crystal Violet.
D2D-27	Preparation of Alizarin.
D2D-28	Preparation of Phenophthalin.
D2D-29	Preparation of Flurescein.
D2D-30	Preparation of Eosin.
D2D-31	Preparation of Indigo.
D2D-32	Occurrence- Composition of Crude oil.
D2D-33	Distillation of the Crude oil.
D2D-34	Synthetic petrol.
D2D-35	Optical activity in Lactic and Tartaric acid,
D2D-36	Fission Reaction and reaction intermediates
D2D-37	Optical, Geometrical and Conformational Isomerism
D2D-38	Resolution of racemic mixture.
D2D-39	Qualitative tests of Proteins.

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